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Biogas, which has been considered as a sustainable and renewable gaseous fuel ( EPA, 2014), is suitable for direct conversion into syngas (i.e., a mixture of H 2 and CO) via a reforming. Renewable power sources have entered the energy markets due to their promising sustainable development, reduced environmental pollution, and enhanced domestic energy supply ( NREL, 2013). Research on renewable energies has been carried out due to concerns related to global warming and depletion of petroleum-based resources.
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The thermodynamic limitation and techno-economics of biogas conversion are also discussed. The synthesis, characterization, lifetime, deactivation, and regeneration of candidate reforming catalysts are discussed in detail. In this paper, we review recent developments in dry, bi-, and tri-reforming, where the CO2 in biogas is used as an oxidant/partial oxidant. New research efforts have explored efficient and effective reforming catalysts, as specifically applied to biogas. Interest also exists due to the role of dry, bi-, and tri-reforming in the capture and utilization of CO2. Although biogas is frequently used in low-value applications such as heating and fuel in engines or even just flared, reforming is an emerging strategy for converting biogas to syngas, which could then be used to obtain high-value-added liquid fuels and chemicals. Interest in novel uses of biogas has increased recently due to concerns about climate change and greater emphasis on renewable energy sources.